Novel hybrid material proves an efficient photodetector

In the last twenty years, metal-organic frameworks (MOFs) have become a coveted material system. So far, these highly porous substances, up to 90 percent of which are composed of empty space, have largely been used to store gases, for catalysis or to slowly release drugs in the human body. “The metal-organic framework compound developed at TU Dresden comprises an organic material integrated with iron ions,” explains Dr. Artur Erbe, head of the “Transport in Nanostructures” group at HZDR’s Institute of Ion Beam Physics and Materials Research. “The special thing about it is that the framework forms superimposed layers with semiconducting properties, which makes it potentially interesting for optoelectronic applications.”

The group had the idea of using the new semiconducting two-dimensional MOF as a photodetector. In order to pursue it further, Himani Arora investigated the semiconductor’s electronic properties. She explored, among others, to what extent the light sensitivity was dependent on temperature and wavelength – and came to a promising conclusion: From 400 to 1575 nanometers, the semiconductor could detect a broad range of light wavelengths. The spectrum of radiation thus goes from ultraviolet to near infrared. “This is the first time we have proved such a broadband photodetection for a photodetector completely based on MOF layers,” the doctoral candidate notes. “These are ideal properties for using the material as an active element in optoelectronic components.”

Small bandgap makes for efficiency

The spectrum of wavelengths a semiconducting material can cover and transform into electrical signals essentially depends on the so-called bandgap. Experts use this term to describe the energetic distance between the valence band and the conduction band of a solid state material. In typical semiconductors, the valence band is completely full, so the electrons cannot move around. The conduction band, on the other hand, is largely empty, so the electrons can move around freely and influence the current flow. While the bandgap in insulators is so big that the electrons cannot jump from the valance band to the conduction band, metal conductors have no such gaps. A semiconductor’s bandgap is just big enough to raise the electrons to the higher energy level of the conduction band by using the light waves. The smaller the bandgap, the lesser the energy required to excite an electron. “As the bandgap in the material we explored is very small, only very little light energy is required to induce the electricity,” Himani Arora explains. “This is the reason for the large range of the detectable spectrum.”

By cooling the detector down to lower temperatures, the performance can be improved yet further because the thermal excitation of the electrons is suppressed. Other improvements include optimizing the component configuration, producing more reliable contacts and developing the material further. The results suggest that the MOF-based photodetectors will have a bright future. Thanks to their electronic properties and inexpensive manufacturing, MOF layers are promising candidates for a raft of optoelectronic applications.

“The next step is to scale the layer thickness,” says Artur Erbe, looking forward. “In the study, 1.7 micrometer MOF films were used to build the photodetector. To integrate them into components, they need to be significantly thinner.” If possible, the aim is to reduce the superimposed layers to 70 nanometers, that is, 25 times smaller than their size. Down to this layer thickness the material should exhibit comparable properties. If the group can prove that the functionality remains the same in these significantly thinner layers, they can then embark on developing it to the production stage.

Publication:

H. Arora, R. Dong, T. Venanzi, J. Zscharschuch, H. Schneider, M. Helm, X. Feng, E. Cánovas, A. Erbe: Demonstration of a broadband photodetector based on a two‐dimensional metal-organic framework, in Advanced Materials, 2020 (DOI: 10.1002/adma.201907063)